Hafnium (new) - Periodic Table of Videos

Periodic Videos
12 May 202314:35
EducationalLearning
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TLDRThe video script delves into the intriguing world of hafnium, element 72, highlighting its unique properties, such as resistance to acids and its impressive flame when finely divided in a Bunsen burner. It uncovers the element's history, including its contentious discovery and naming, and explores its applications, from rocket nozzles to potential use in smartphones, due to its role as an insulator in transistors and as a possible replacement for indium in transparent conductive layers.

Takeaways
  • 🔥 Hafnium is an exciting element that burns well and has various applications, including in mobile phones and nuclear reactors.
  • 📊 Hafnium is element number 72 on the periodic table and is in the same group as titanium and zirconium.
  • 🗓️ 2023 marks the 100th anniversary of the publication of the paper announcing hafnium's discovery.
  • 💬 There was a significant scientific debate in the early 20th century regarding the discovery and naming of hafnium.
  • 🔨 Hafnium is a tough metal that doesn't easily dissolve in acids, even resistant to fuming nitric acid.
  • 🌌 Aqua regia, a mixture of hydrochloric and concentrated nitric acid, can dissolve hafnium, albeit slowly.
  • 🔍 The discovery of hafnium was initially confused with the discovery of rare earths and its correct placement in the periodic table was debated.
  • 🏆 Hafnium was named after Copenhagen, believed to be from the Latin name 'Hafnia', and was supported by Niels Bohr.
  • 🔥 Hafnium demonstrates high-temperature burning when finely divided, producing a visually impressive flame.
  • ⚙️ Historically, hafnium had limited uses but is now important in electronics, particularly for making computer chips.
  • 📱 There is potential for hafnium to replace indium in the transparent, electrically conducting layers of smartphone screens due to indium scarcity.
Q & A
  • What is hafnium and what is its significance?

    -Hafnium is element number 72 on the periodic table, belonging to the same group as titanium and zirconium. It has various exciting properties, including its ability to burn well, its use in high-temperature applications, and its importance in electronics and nuclear technology.

  • Why is the year 2023 significant for hafnium?

    -2023 marks the 100th anniversary of the discovery of hafnium, as the paper announcing its discovery was published on January 20, 1923.

  • What was the controversy surrounding the discovery of hafnium?

    -The controversy arose due to a previous claim by a French chemist who thought he discovered element 72 and named it celtium. However, this claim was later proven incorrect, leading to skepticism when the actual discovery was announced by a Hungarian chemist and a Dutch colleague in 1923.

  • How did hafnium get its name?

    -Hafnium was named after Copenhagen, Denmark, where it was discovered. The name is derived from the Latin word for Copenhagen, which they believed to be 'Hafnia'.

  • Why is hafnium difficult to dissolve in acids?

    -Hafnium is resistant to most acids due to its chemical properties. Even strong acids like fuming nitric acid and concentrated hydrochloric acid do not affect it until aqua regia, a mixture of hydrochloric and nitric acids, is used.

  • What is the significance of hafnium's resistance to acids in its discovery?

    -The resistance to acids was a key factor in the discovery process, as it helped differentiate hafnium from other elements, especially since it was found as an impurity in zirconium minerals.

  • How does hafnium's burning properties relate to its use in technology?

    -Hafnium's high-temperature burning properties indicate its suitability for applications that require materials to withstand extreme heat, such as in rocket nozzles and potentially in future electronic displays.

  • What is the current primary use of hafnium in the electronics industry?

    -Hafnium is primarily used in the electronics industry for making computer chips due to its oxide's insulating properties, which are essential for the miniaturization of transistors.

  • How does hafnium's neutron absorption affect its use in nuclear reactors?

    -Hafnium's ability to absorb neutrons makes it a poor impurity for nuclear reactors, as it can interfere with the nuclear chain reaction. This property is a disadvantage when hafnium is found as a byproduct in zirconium, which is used for cladding fuel rods in reactors.

  • What potential future use for hafnium is mentioned in the script?

    -The script mentions a potential future use of hafnium in smartphone screens as a replacement for indium in the electrically conducting layer, due to indium's scarcity and hafnium's properties.

  • What role did famous scientists play in the naming controversy of hafnium?

    -Niels Bohr supported the name 'hafnium,' while Ernest Rutherford supported 'celtium.' Both scientists were influential figures who tried to sway the decision of the editor of Nature, where the discovery was published.

Outlines
00:00
🔍 Discovery and Characteristics of Hafnium

Brady's inquiry about hafnium reveals its fascinating properties, such as its ability to burn well, its high cost, and its significance in both mobile phones and nuclear reactors. Element 72 on the periodic table, hafnium, is related to titanium and zirconium. Discovered in 1923, its confirmation led to major scientific disputes. Tony Lippman provided samples for experimentation, highlighting hafnium's resistance to acids except for aqua regia. This section details Neil's unsuccessful attempts to dissolve hafnium with various acids, ultimately succeeding with aqua regia.

05:03
🧪 Controversial Discovery of Hafnium

The discovery of hafnium was contentious. Initially claimed by French chemist Urbain, his findings were doubted due to previous errors. In 1923, Hungarian chemist Hevesy and Dutch colleague Coster, working in Denmark, announced hafnium's discovery, naming it after Copenhagen. The French opposed this due to post-World War I tensions and patriotic sentiments. Despite political and scientific lobbying, hafnium's association with zirconium minerals led to its acceptance over celtium, which would have confused students with its similarity to cerium.

10:03
🔥 Hafnium’s Unique Properties and Modern Applications

Hafnium's discovery and properties are explored further. Neil’s experimentation with hafnium filings demonstrates its impressive burning characteristics, similar to zirconium. Hafnium's historical lack of applications is noted, with recent developments in electronics, particularly in high-purity transistors and potential replacements for indium in smartphone screens, highlighting its newfound importance. The video concludes by inviting viewers to support the channel via Patreon and hints at hafnium's potential future in technology.

Mindmap
Keywords
💡Hafnium
Hafnium is a chemical element with the symbol Hf and atomic number 72. It is a lustrous, silvery gray, tetravalent transition metal. In the video, hafnium is highlighted for its exciting properties, such as its ability to burn well and its importance in various applications including mobile phones and nuclear reactors. The script discusses its discovery, its chemical resistance to acids, and its use in high-tech industries.
💡Periodic Table
The periodic table is a tabular arrangement of the chemical elements, ordered by their atomic number, electron configuration, and recurring chemical properties. The video script mentions that hafnium is element 72 and is in the same group as titanium and zirconium, emphasizing its position on the periodic table as crucial to understanding its properties and history.
💡Discovery
The term 'discovery' in the script refers to the historical event in 1923 when the existence of hafnium was first proven through a published paper. This discovery is a central theme of the video, illustrating the scientific process and the controversy surrounding the naming and recognition of the element.
💡Chemical Reactions
Chemical reactions are processes that lead to the transformation of one set of chemical substances to another. The script describes the attempts to dissolve hafnium in various acids, such as fuming nitric acid and aqua regia, demonstrating its chemical inertness and the eventual reaction that pleases Neil, one of the characters in the video.
💡Aqua Regia
Aqua regia is a highly corrosive mixture of concentrated hydrochloric acid and concentrated nitric acid, capable of dissolving noble metals such as gold. In the script, aqua regia is used to attempt the dissolution of hafnium, showing its remarkable resistance to corrosion and its eventual reaction, which is slower than that of gold.
💡Neutron Absorption
Neutron absorption is the process by which an atomic nucleus captures a neutron, leading to a change in the nucleus. The script mentions that hafnium has a high neutron absorption cross-section, making it undesirable in nuclear reactors where zirconium is used as fuel rod cladding due to the presence of hafnium as an impurity.
💡Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. It is a lustrous, grey-white, strong transition metal that resembles hafnium. The script discusses zirconium's role as a source of hafnium and its use in the nuclear industry, as well as its similar chemical properties and flammability when finely divided.
💡Transistors
Transistors are semiconductor devices used to amplify or switch electronic signals and electrical power. They are fundamental to modern electronic devices. The script explains that as transistors get smaller, hafnium oxide has become an important insulating material in the production of computer chips, highlighting the element's relevance in the electronics industry.
💡Indium
Indium is a chemical element with the symbol In and atomic number 49. It is a post-transition metal that is soft, malleable, and easily fusible. The script mentions indium as the current material used in the transparent conductive layers of smartphone screens, but notes that it is becoming scarce, and hafnium is being considered as a potential replacement.
💡Samsung
Samsung is a South Korean multinational conglomerate known for its electronics, including smartphones. The script refers to a patent from Samsung that discusses the use of hafnium in transparent screens for future smartphones, indicating the potential future applications of hafnium in consumer technology.
💡Bunsen Burner
A Bunsen burner is a common laboratory apparatus that produces a single open gas flame, used for heating, sterilization, and combustion. In the script, the burning of hafnium in a Bunsen flame is used to demonstrate its flammability when in a finely divided state, creating an artistic and visually impressive effect.
Highlights

Hafnium, element 72, is more exciting than expected with its unique properties and applications.

Hafnium burns well and has intriguing links to mobile phones and nuclear reactors.

Hafnium is expensive and was discovered over 100 years ago in 1923.

The discovery of hafnium was accompanied by a major scientific controversy in the early 20th century.

Hafnium is difficult to work with, as demonstrated by the struggle to straighten it with hands and a hammer.

Hafnium is resistant to common acids, including fuming nitric and concentrated hydrochloric acid.

Aqua regia, a mixture of hydrochloric and nitric acid, is capable of dissolving hafnium.

The discovery of hafnium was initially confused with the discovery of rare earths and other elements.

Hafnium was named after Copenhagen, reflecting its discovery location in Denmark.

The naming of hafnium was influenced by patriotism and scientific rivalry.

Hafnium's discovery was supported by famous physicists Niels Bohr and Ernest Rutherford.

Hafnium is found as an impurity in zirconium and was successfully isolated by looking in the right minerals.

Hafnium dust produces a visually impressive flame when burned in a Bunsen burner.

Hafnium's high-melting point made it useful in the Apollo lunar lander rocket nozzles.

Hafnium's neutron-absorbing properties make it a disadvantage in nuclear reactors but a byproduct of the zirconium industry.

Hafnium oxide is an excellent insulator for computer chips, increasing its demand in electronics.

Hafnium may replace indium in smartphone screens due to indium scarcity.

Samsung has patented the use of hafnium in transparent conductive screens for mobile devices.

Transcripts
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