Half Life Chemistry Problems - Nuclear Radioactive Decay Calculations Practice Examples

The Organic Chemistry Tutor
22 Sept 201618:02
EducationalLearning
32 Likes 10 Comments

TLDRThe video script provides an in-depth exploration of the concept of half-life, particularly in the context of chemistry and radioactive decay. It begins with a practical example involving iodine-131, demonstrating how to calculate the remaining mass after a given number of half-lives, both through direct calculation and using the formula involving the rate constant (k). The script then covers similar calculations for sodium-24 and oxygen-15, highlighting the use of equations to find decay times and remaining fractions after specific numbers of half-lives. The video concludes with determining the half-life of an unknown element, element X, from decay data. Throughout, the script emphasizes the importance of understanding half-life as a fundamental concept in chemistry and physics, and it offers both conceptual and mathematical approaches to tackle related problems.

Takeaways
  • πŸ§ͺ The half-life of a substance represents the time it takes for half of the substance to decay into another element.
  • ⏳ Iodine-131 has a half-life of 8 days, meaning that after 8 days, half of the initial amount will have transformed into another element.
  • πŸ“‰ To calculate the remaining amount after a certain period, you can use either a simple step-by-step decay calculation or a mathematical equation involving the rate constant (K).
  • πŸ”’ The rate constant (K) is found by dividing the natural logarithm of 2 by the half-life of the substance.
  • πŸ“Œ The formula for radioactive decay is AF = Ao * e^(-KT), where AF is the final amount, Ao is the initial amount, K is the rate constant, and T is time.
  • πŸ•’ For the example of Sodium-24, it takes 60 hours for 750 grams to decay to 50 grams, which is four half-lives of 15 hours each.
  • πŸ•— The half-life of Oxygen-15 is 2 minutes, and after five half-lives, which is 10 minutes, 1/32 of the original sample remains.
  • πŸ”§ To convert a percentage to a decimal, divide by 100 or move the decimal point two places to the left.
  • πŸ”Ž The fraction remaining after a certain number of half-lives can be found by dividing 1 by 2 raised to the power of the number of half-lives.
  • πŸ•’ For Element X, which decays from 512 grams to 4 grams in 35 days, the half-life can be calculated by dividing the total time by the number of half-lives it took to reach the final amount.
  • πŸ“ The half-life can also be determined using the formula half-life = ln(2) / K, where K is the rate constant calculated from the decay equation.
Q & A
  • What is the half-life of iodine-131 mentioned in the video?

    -The half-life of iodine-131 is 8 days.

  • How much iodine-131 will remain after 32 days if you start with 200 grams?

    -After 32 days, 12.5 grams of iodine-131 will remain.

  • What is the formula for calculating the remaining amount of a substance after decay?

    -The formula is AF = Ao * e^(-kt), where AF is the final amount, Ao is the initial amount, k is the rate constant, and t is time.

  • What is the rate constant (K) for iodine-131 given its half-life?

    -The rate constant K for iodine-131 is 0.08664 when calculated using the natural log of 2 divided by the half-life of 8 days.

  • How many half-lives does it take for 800 grams of sodium-24 to decay to 50 grams?

    -It takes four half-lives for 800 grams of sodium-24 to decay to 50 grams.

  • What is the half-life of sodium-24?

    -The half-life of sodium-24 is 15 hours.

  • How long will it take for 750 grams of sodium-24 to decay?

    -It will take 60 hours for 750 grams of sodium-24 to decay.

  • What fraction of a sample of oxygen-15 will remain after five half-lives?

    -After five half-lives, 1/32 of a sample of oxygen-15 will remain.

  • What is the formula to convert a percentage to a decimal?

    -To convert a percentage to a decimal, divide by 100 or move the decimal point two units to the left.

  • How many half-lives does it take for a 512 gram sample of element X to decay to 4 grams?

    -It takes seven half-lives for a 512 gram sample of element X to decay to 4 grams.

  • What is the half-life of element X given its decay from 512 grams to 4 grams over 35 days?

    -The half-life of element X is approximately 5 days.

  • How can you calculate the rate constant (K) for radioactive decay?

    -The rate constant (K) can be calculated using the formula K = ln(2) / half-life of the substance.

Outlines
00:00
πŸ”¬ Understanding Half-Life: Iodine-131 Example

This paragraph introduces the concept of half-life in the context of radioactive decay, specifically using iodine-131 with a half-life of 8 days as an example. It explores two methods to determine the remaining amount of iodine-131 after 32 days: a straightforward conceptual approach and a mathematical equation involving the rate constant K. The conceptual approach involves sequentially dividing the initial amount by two for each half-life period, resulting in 12.5 grams remaining after 32 days. The mathematical approach calculates the rate constant K as the natural logarithm of 2 divided by the half-life, then uses this in an equation to find the final amount (AF), which closely matches the conceptual method's result.

05:00
⏳ Time to Decay for Sodium-24

The second paragraph discusses the decay time for a sample of sodium-24 with a half-life of 15 hours. It starts with 800 grams of sodium-24 and asks how long it will take for 750 grams to decay, leaving 50 grams unchanged. The explanation involves counting the number of half-lives (four in this case) and multiplying this by the half-life duration to get a total time of 60 hours. An alternative method uses the natural logarithm to find the rate constant K and then solve for time (t), which confirms the 60-hour duration.

10:03
πŸ“‰ Fraction Remaining After Multiple Half-Lives: Oxygen-15

The third paragraph deals with calculating the fraction of a sample of oxygen-15 that remains after five half-lives, given a half-life of 2 minutes. It explains a step-by-step reduction of the sample size by half for each half-life, resulting in 3.125% remaining after five half-lives. The paragraph also demonstrates how to convert this percentage to a decimal and then to a fraction, identifying 1/32 as the correct fraction remaining. Additionally, it presents a faster method for such calculations by realizing that the fraction remaining after 'n' half-lives is 1 divided by 2 to the power of 'n'.

15:03
βš—οΈ Determining the Half-Life of Element X

The final paragraph is about finding the half-life of an element referred to as 'Element X'. Given that it takes 35 days for a 512-gram sample to decay to 4 grams, the paragraph outlines a method to determine the number of half-lives that occur in this process (seven half-lives). It then calculates the half-life by dividing the total time by the number of half-lives, resulting in a half-life of five days. The paragraph also shows how to use the natural logarithm to find the rate constant K and subsequently the half-life, which corroborates the initial finding.

Mindmap
Keywords
πŸ’‘Half-Life
Half-life is a concept in nuclear chemistry that describes the time required for half of a given amount of a radioactive substance to decay. In the video, it is central to solving problems related to the decay of substances like iodine-131 and sodium-24. For example, iodine-131 has a half-life of 8 days, which means that after 8 days, half of the initial amount would have decayed.
πŸ’‘Radioactive Decay
Radioactive decay is a random process by which unstable atomic nuclei lose energy by emitting radiation. The video uses this concept to calculate how much of a substance remains after a certain period. For instance, it is used to determine the amount of iodine-131 remaining after 32 days, starting with an initial sample of 200 grams.
πŸ’‘Rate Constant (k)
The rate constant, denoted as 'k', is a proportionality factor used in the radioactive decay equation. It is calculated as the natural logarithm of 2 divided by the half-life of the substance. The video explains how to find 'k' for iodine-131 and sodium-24 and how it is used in the decay equation to find the remaining amount after a given time.
πŸ’‘First Order Kinetics
First order kinetics refers to a type of chemical reaction where the rate of the reaction depends on the concentration of one reactant. In the context of the video, radioactive decay is treated as a first order process, meaning the decay rate is proportional to the amount of substance present, which is why the same equation can be used for different decay problems.
πŸ’‘Natural Logarithm (ln)
The natural logarithm, denoted as 'ln', is the logarithm to the base 'e' (approximately 2.71828). It is used in the calculation of the rate constant 'k' for radioactive decay. In the video, the natural logarithm of 2 is used to determine 'k' for substances like iodine-131 and sodium-24.
πŸ’‘Sodium-24
Sodium-24 is a radioactive isotope of sodium with a half-life of 15 hours. It is used in the video as an example to illustrate how to calculate the time it takes for a certain amount of the substance to decay, starting with an initial sample of 800 grams.
πŸ’‘Iodine-131
Iodine-131 is a radioactive isotope of iodine with a half-life of 8 days. The video uses iodine-131 to demonstrate how to calculate the amount of a substance that remains after a certain number of half-lives, starting with an initial sample of 200 grams.
πŸ’‘Exponential Decay
Exponential decay is a mathematical model that describes a quantity decreasing at a rate proportional to its current value, often seen in radioactive decay. The video discusses this concept in the context of the decay equation, where the remaining amount of a substance decreases exponentially over time.
πŸ’‘Half-Life Equation
The half-life equation is a formula used to calculate the amount of a radioactive substance remaining after a certain period. In the video, the equation is used to find the remaining amount of iodine-131 after 32 days and sodium-24 after a specific time, given their respective half-lives.
πŸ’‘Sample Decay
Sample decay refers to the process of a radioactive sample decreasing in quantity as it undergoes radioactive decay. The video uses this concept to explain how to determine the amount of a substance that has decayed over time, such as how much of an 800-gram sample of sodium-24 remains after a certain period.
πŸ’‘Element X
Element X is a hypothetical radioactive element used in the video to demonstrate how to calculate the half-life of a substance when given the initial and final amounts and the time taken for the decay. It helps illustrate the process of using the decay equation to solve for the half-life when other variables are known.
Highlights

The video discusses the concept of half-life, particularly in the context of chemistry and radioactive decay.

Iodine-131 has a half-life of 8 days, and the problem involves calculating the remaining amount after 32 days.

Two methods are presented for solving decay problems: one conceptual and one using an equation.

The conceptual method involves understanding that half-life is the time for half of a substance to decay.

Using the conceptual method, it's determined that 12.5 grams of Iodine-131 will remain after 32 days.

The rate constant K is introduced as a way to solve decay problems using an equation, where K = ln(2) / half-life.

The equation AF = Ao * e^(-KT) is used to find the final amount of a substance after decay, where AF is the final amount, Ao is the initial amount, K is the rate constant, and T is time.

The rate constant K for Iodine-131 is calculated to be approximately 0.08664, which is then used in the equation to find the final amount remaining.

An example with Sodium-24 is used to illustrate how to find the time it takes for a certain amount of a substance to decay.

The half-life of Sodium-24 is given as 15 hours, and the problem is to find out how long it takes for 750 grams to decay, leaving 50 grams.

By using the half-life and the decay equation, it's shown that it takes 60 hours for 750 grams of Sodium-24 to decay to 50 grams.

Another example involves Oxygen-15 with a half-life of 2 minutes, and the problem is to find the fraction remaining after five half-lives.

The fraction remaining after five half-lives is found to be 1/32 by both conceptual reasoning and mathematical calculation.

A faster method for finding the fraction remaining after multiple half-lives involves dividing 1 by 2 raised to the power of the number of half-lives.

A problem involving Element X with a sample size of 512 grams decaying to 4 grams in 35 days is used to determine the half-life of Element X.

By calculating the rate constant K and using the decay equation, the half-life of Element X is found to be approximately 5 days.

The video concludes with a summary of the methods and equations used for solving radioactive decay problems.

Transcripts
Rate This

5.0 / 5 (0 votes)

Thanks for rating: