Making my favorite liquid carcinogen

NileRed
26 Sept 201925:37
EducationalLearning
32 Likes 10 Comments

TLDRIn this thrilling chemistry experiment, the creator revisits their favorite chemical, chromel chloride, a chromium-based compound known for its volatility, toxicity, and vibrant color. They meticulously produce it from potassium dichromate and sodium chloride, using a blender for optimal mixing. The process involves a dangerous yet fascinating reaction with concentrated sulfuric acid, resulting in a blood-like liquid. The creator explores the chemical's properties, including its reactivity with water, ethanol, and aniline, culminating in a captivating demonstration of its potential as a powerful oxidizer and its unique interaction with toluene.

Takeaways
  • 🧪 The creator's favorite chemical is chromel chloride, a chromium-based compound, due to its volatile, toxic, and corrosive properties.
  • 🛒 The process begins with sourcing chromium from potassium dichromate, purchased from eBay, and sodium chloride (table salt) from a grocery store.
  • 🔬 To avoid interference, pickling salt is used for its purity, although regular iodized salt might have been sufficient.
  • 🌐 A blender is used to mix the ingredients finely to improve the reaction efficiency compared to a mortar and pestle.
  • 🔥 The reaction involves mixing the salt and dichromate powder with concentrated sulfuric acid, which is added slowly to the mixture.
  • 🌡 The setup includes a condenser column and thermometer to control the reaction temperature and prevent overheating.
  • 💧 The reaction produces chromel chloride along with side products like potassium bisulfate and sodium bisulfate, releasing a lot of heat.
  • 🚫 Safety is paramount; the process is conducted in a fume hood to prevent inhalation of toxic and corrosive fumes.
  • 🔬 The creator filters the chromel chloride to remove solid chunks formed by reaction with air moisture and measures the yield, which is higher than expected.
  • 🔮 Experiments with chromel chloride include adding it to various substances like water, ethanol, aniline, and sulfur, each demonstrating unique reactions.
  • 🍒 An interesting application of chromel chloride is its potential to convert toluene into benzaldehyde, known for its cherry smell, through a reaction known as the Attard reaction.
Q & A
  • What is the speaker's favorite chemical compound and why is it their favorite?

    -The speaker's favorite chemical compound is chromel chloride. They like it because it has a combination of interesting properties such as being toxic, carcinogenic, highly corrosive, potentially explosive, and highly volatile, along with having a vibrant color similar to blood.

  • On a scale of one to ten, how dangerous is chromel chloride according to the speaker?

    -The speaker rates chromel chloride as a five on a scale of danger, with one being as harmless as table salt and ten being as dangerous as sarin nerve gas.

  • What are the main ingredients needed to make chromel chloride according to the script?

    -The main ingredients needed to make chromel chloride are potassium dichromate and sodium chloride (table salt), with pickling salt being preferred to avoid iodine additives.

  • Why did the speaker use a blender to mix the potassium dichromate and sodium chloride?

    -The speaker used a blender to ensure a very fine and well-mixed powder, which they believe would make the reaction more efficient compared to using a mortar and pestle as done previously.

  • What is the purpose of using concentrated sulfuric acid in the production of chromel chloride?

    -Concentrated sulfuric acid is used in the reaction to prevent any chromel chloride from leaking out by greasing the joints of the reaction setup. It is also used in the reaction process to produce chromium trioxide and hydrogen chloride gas, which then react to form chromel chloride.

  • What safety measures did the speaker take while handling chromel chloride?

    -The speaker took several safety measures, including working in a fume hood to prevent the inhalation of toxic and corrosive vapors, using a heating mantle to control the reaction temperature, and sealing the final product with a sulfuric acid-coated stopper to prevent leakage.

  • What was the yield percentage of chromel chloride obtained by the speaker in this process?

    -The yield percentage of chromel chloride obtained by the speaker was 67%, based on the amount of dichromate used, which was higher than their previous yield of 52%.

  • How did the speaker demonstrate the difference between chromel chloride and bromine?

    -The speaker demonstrated the difference by adding each chemical to a dish and observing their reactions. Chromel chloride showed a vibrant red color and a creeping effect along the glass, while bromine was darker, did not creep, and its vapors sank more due to its density.

  • What is the Attard reaction that the speaker mentioned at the end of the script?

    -The Attard reaction is not explicitly described in the script, but it is implied to be a future experiment involving chromel chloride that the speaker is interested in conducting.

  • Why did the speaker decide to stop taking most sponsorships and rely on ad revenue and Patreon?

    -The speaker decided to stop taking most sponsorships to maintain independence and avoid the constraints of ads in their videos. They started YouTube memberships to build a small, personal community and to support the channel financially without relying solely on ad revenue.

Outlines
00:00
🧪 The Fascination with Chromel Chloride

The speaker introduces their favorite chemical, chromel chloride, a chromium-based compound known for its toxicity, carcinogenic properties, corrosiveness, and potential explosiveness. Despite its dangerous nature, the speaker appreciates its volatile and colorful characteristics, comparing its risk level to everyday substances like table salt and sarin gas. The process of creating chromel chloride involves sourcing chromium from potassium dichromate and sodium chloride (preferably pickling salt to avoid iodine interference). The preparation involves blending these ingredients thoroughly, which is crucial for the reaction's efficiency. The setup for the reaction includes an addition funnel, a three-way adapter, a thermometer, and a condenser column, all designed to prevent leakage and control the reaction.

05:02
🔥 The Reaction Process of Chromel Chloride

The video script details the chemical reactions involved in producing chromel chloride. Initially, sulfuric acid reacts with salt and dichromate to form chromium trioxide and hydrogen chloride gas. These products then combine to form chromel chloride. The importance of thorough mixing is emphasized to ensure the hydrogen chloride reacts promptly with chromium trioxide, preventing its escape as a gas. The reaction is exothermic, releasing heat, and can potentially get out of control if not conducted with cold acid. After adding the acid, the mixture is allowed to settle before additional cold sulfuric acid is introduced, causing the reaction to bubble and release hydrogen chloride gas. The speaker uses a heating mantle to boil the chromel chloride, separating it from side products, and condenses the vapors using an ice bath. The process concludes with the collection of the red, blood-like liquid in a flask, sealed with a sulfuric acid-coated stopper.

10:04
🌡️ Handling and Testing Chromel Chloride

The speaker discusses the handling and testing of chromel chloride, noting its tendency to react with moisture in the air and form solid chunks. To purify the chemical, it is left to sit overnight, allowing solids to separate, and then filtered. The yield is measured, revealing a 67% efficiency, attributed to the use of a blender for mixing the initial ingredients. The speaker then explores the chemical's properties by adding it to a dish, observing its dark color and fuming nature, and comparing it to bromine. Chromel chloride is shown to react with glass, and its vapors are noted to be toxic and corrosive. The speaker also demonstrates the chemical's reactivity with sodium sulfite, which reduces it to a safer, green oxidation state.

15:06
💥 Exploring the Reactivity of Chromel Chloride

The script continues with experiments on the reactivity of chromel chloride. It is added to water, demonstrating its density and reaction to produce hydrogen chloride gas. The speaker also tests its potential explosiveness by burning it on a watch glass, noting its decomposition into chlorine, oxygen, and chromium compounds. Further tests involve adding chromel chloride to ethanol, aniline, and sulfur, observing mild reactions and comparing these to other strong oxidizers. The reaction with toluene is highlighted, forming a complex that the speaker anticipates might ignite but does not. The potential to convert toluene to benzaldehyde, a chemical with a cherry smell, is mentioned, though the experiment does not yield a detectable scent.

20:07
🏺 Storing Chromel Chloride and Channel Updates

The final paragraph covers the storage of chromel chloride, which is prone to leakage even in well-sealed containers. The speaker demonstrates making an ampule by heating a test tube and stretching it to form a thin neck, which is then filled with the chemical and sealed by melting the glass. The ampule is tested for leaks and stored. The speaker also discusses their decision to rely on ad revenue and Patreon for channel support, explaining their preference for a more personal community and the launch of YouTube memberships as an alternative. The video concludes with a thank you to Patreon supporters and an invitation for viewers to join the YouTube community for additional perks.

Mindmap
Keywords
💡Chromel Chloride
Chromel chloride, also known as chromium(VI) chloride or chromyl chloride, is a highly toxic and corrosive chemical compound. In the video, it is the central subject of the experiment, being synthesized and explored for its properties. The script describes its vivid color, its volatility, and its reactivity with other substances, which are all key aspects of the video's theme of chemical experimentation.
💡Potassium Dichromate
Potassium dichromate is an inorganic compound that serves as a starting material in the synthesis of chromel chloride. It is described as a common and cheap chromium-based compound in the script. The video details its role in the preparation process, highlighting its importance in the chemical reaction that leads to the formation of chromel chloride.
💡Sodium Chloride
Sodium chloride, commonly known as table salt, is another ingredient in the production of chromel chloride. The script mentions the use of pickling salt, which is pure sodium chloride, to avoid the presence of iodine that could interfere with the reaction. This term is relevant to the video's theme of precision in chemical experimentation.
💡Concentrated Sulfuric Acid
Concentrated sulfuric acid is used in the script as a reagent in the synthesis of chromel chloride. It is depicted as a highly reactive and dangerous chemical that requires careful handling. The video emphasizes the risks associated with its use, which ties into the overarching theme of the video about the balance between danger and excitement in chemical experiments.
💡Reduction
Reduction is a chemical reaction where a substance gains electrons, typically resulting in a lower oxidation state. In the script, sodium sulfite is used as a reducing agent to reduce chromel chloride to a safer form. This concept is key to understanding the video's exploration of chemical reactions and the transformation of substances.
💡Oxidation State
Oxidation state is a measure of the degree of oxidation of an atom in a substance. The video script discusses the reduction of chromel chloride from its 6+ oxidation state to a 3+ state. This concept is integral to understanding the chemical transformations that occur during the experiments shown in the video.
💡Condenser Column
A condenser column is a piece of laboratory equipment used to cool gases and condense them back into liquids. In the script, it is used to condense the vapors of chromel chloride during the distillation process. The use of the condenser column is a practical example of the video's focus on the technical aspects of chemical distillation.
💡Distillation
Distillation is a process used to separate components from a liquid mixture by selective evaporation and condensation. The script describes the distillation of chromel chloride to purify it from side products. This process is a central technique in the video's narrative of chemical synthesis.
💡Toxicity
Toxicity refers to the degree to which a substance can cause harm to a living organism. The script repeatedly mentions the toxicity of chromel chloride, emphasizing the need for safety precautions in chemical handling. This concept is crucial to the video's theme of the inherent dangers in chemical experimentation.
💡Corrosiveness
Corrosiveness is the ability of a substance to wear away or damage other materials. The script describes chromel chloride as highly corrosive, which is an important safety consideration in the video's depiction of chemical experimentation. It illustrates the video's theme of the dual nature of chemicals as both fascinating and hazardous.
💡Hypergolic
Hypergolic refers to substances that ignite spontaneously upon contact with certain other substances. In the script, the video explores the hypergolic properties of chromel chloride when it comes into contact with aniline and ethanol. This concept is part of the video's exploration of the reactivity and potential energy of chemicals.
Highlights

Experimenter's favorite chemical is chromel chloride due to its intriguing properties.

Chromel chloride is toxic, carcinogenic, highly corrosive, potentially explosive, and volatile, yet has a fascinating color.

A scale from one to ten ranks chromel chloride at five in terms of danger, compared to table salt and sarin gas.

Experimenter enjoys working with dangerous chemicals and finds chromel chloride's properties exciting.

The process of making chromel chloride involves potassium dichromate and sodium chloride as main ingredients.

Iodine in table salt might interfere with the reaction, leading to the use of pickling salt.

Mixing ingredients with a blender improves the reaction efficiency compared to a mortar and pestle.

Concentrated sulfuric acid is added to the mixture to initiate the reaction for chromel chloride production.

The reaction setup includes a condenser column and thermometer to control the process.

Hydrogen chloride gas is produced as a byproduct and needs to be carefully managed due to its corrosiveness.

Chromel chloride's boiling point is 117 C, and the goal is to separate it from side products by heating.

A fume hood is used to ensure safety during the experiment by containing toxic and corrosive vapors.

The final product is a vibrant red liquid resembling blood, with a yield of 67% from the experiment.

Chromel chloride reacts with water, creating a unique effect with bubbles sticking to its dense liquid.

Experimenter tests chromel chloride's flammability and its reaction with various substances like ethanol and aniline.

Ampules are used for safe storage of chromel chloride due to its tendency to corrode containers.

Cleanup and additional experiments are documented in a separate video on the Nile Blue channel.

Experimenter has chosen to rely on ad revenue and Patreon to maintain independence and support the channel.

Transcripts
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