A close look at supercritical carbon dioxide CO2

Applied Science
3 Sept 201107:58
EducationalLearning
32 Likes 10 Comments

TLDRIn this video, the creator showcases a homemade plastic chamber for holding liquid CO2 and explains its construction and function. Using an aluminum base with acrylic sides and a flexible fiberglass heater, the chamber can heat CO2 to a supercritical state, blending liquid and gas phases. The creator details the process, including pressure readings and design challenges, and demonstrates reversing the supercritical state using dry ice. Potential applications for supercritical CO2, such as decaffeinating coffee beans and dry cleaning, are also discussed. Suggestions for future experiments are welcomed.

Takeaways
  • 🛠️ The presenter has built a plastic chamber from aluminum and acrylic to hold liquid CO2.
  • 🔥 The chamber is designed to be heated slowly using a strip heater, typically used for bending acrylic or heating pipes.
  • 📈 A pressure gauge is used to monitor the pressure inside the chamber, which initially reads about 700 PSI.
  • 🔩 A thermacouple is inserted through a tiny drilled hole for more accurate temperature readings.
  • 🌡️ The CO2 inside the chamber begins to boil when the heater is turned on, indicating a phase change.
  • 🔁 After the boiling stops and the chamber is shaken, the liquid and gas phases of CO2 blend together, creating a supercritical state.
  • ❄️ To transition back to two phases, dry ice is used to cool the chamber rapidly, separating the liquid and gas phases again.
  • 🔧 The chamber was constructed by machining an aluminum disc, cutting an O-ring groove, and assembling it with acrylic parts and O-rings.
  • 💡 The presenter encountered a problem with pressure building before the chamber could be sealed, which deformed the O-rings.
  • 🧪 The chamber was designed to withstand much higher pressures, up to 2,000 to 4,000 PSI, even though supercritical CO2 occurs around 1,100 PSI.
  • 🚀 The presenter plans to experiment with supercritical CO2 for applications such as decaffeinating green coffee beans and dry cleaning.
Q & A
  • What is the main purpose of the plastic chamber project described in the script?

    -The main purpose of the plastic chamber project is to demonstrate the process of transitioning liquid CO2 to a supercritical state and then back to two distinct phases, using heating and cooling methods.

  • What materials were used to construct the chamber?

    -The chamber is constructed from an aluminum piece with acrylic on the front and back.

  • What type of heater is used to heat the chamber?

    -A strip heater, typically used for bending acrylic or heating pipes, is used to heat the chamber.

  • How is the liquid CO2 heated inside the chamber?

    -The liquid CO2 is heated by wrapping the strip heater around the chamber.

  • What is the initial pressure reading on the pressure gauge before heating the CO2?

    -The initial pressure reading on the pressure gauge is about 700 PSI.

  • What method was used to measure the temperature inside the chamber?

    -A thermocouple was inserted through a tiny drilled hole to measure the temperature inside the chamber.

  • What happens when the CO2 reaches a supercritical state?

    -When the CO2 reaches a supercritical state, the density between the liquid and gas phase becomes so similar that they blend together, forming one continuous phase.

  • How is the chamber cooled down to transition back from a supercritical state to two distinct phases?

    -The chamber is cooled down by holding a piece of dry ice against the aluminum exterior to rapidly decrease the temperature.

  • What was the issue encountered when filling the chamber with liquid CO2?

    -The issue encountered was the pressure build-up before the chamber could be sealed properly, which deformed the O-ring due to the high pressure during the sealing process.

  • What design considerations were made for the acrylic thickness in the chamber?

    -Engineering formulas were used to determine the thickness of the acrylic, anticipating higher pressures up to 2,000 to 4,000 PSI.

  • What are some potential applications of supercritical CO2 mentioned in the script?

    -Some potential applications of supercritical CO2 include extracting caffeine from green coffee beans and dry cleaning to remove oily substances without using water or hydrocarbon solvents.

Outlines
00:00
🔧 Building a Liquid CO2 Chamber

The video script introduces a DIY project involving the construction of a plastic chamber designed to hold liquid CO2. The creator uses aluminum and acrylic for the chamber's construction, incorporating a flexible fiberglass strip heater typically used for bending acrylic to heat the chamber slowly. The purpose of the heater is to increase the temperature, causing the liquid CO2 to boil and eventually reach a supercritical state where the distinction between liquid and gas phases disappears. The creator also mentions the use of a pressure gauge and a thermacouple for monitoring, and the process of transitioning the CO2 back to a two-phase state using dry ice. The video provides a step-by-step explanation of the chamber's assembly, including the challenges faced during the construction process.

05:02
🌡 Experimenting with Supercritical CO2

In the second paragraph, the script discusses the issues encountered with the CO2 chamber, specifically the absence of a valve which complicates the filling process and leads to high pressure before the chamber is sealed. The creator had to use engineering formulas to determine the necessary thickness of the acrylic to withstand anticipated pressures, but the actual pressure remained under 2,000 PSI, much lower than expected. The script also outlines safety precautions taken during the initial testing phase, such as setting up the chamber in a shop corner with remote monitoring. The creator expresses interest in using supercritical CO2 for extracting caffeine from green coffee beans and for dry cleaning purposes, highlighting the commercial potential of this technology. The video concludes with an invitation for viewers to suggest other applications for supercritical CO2.

Mindmap
Keywords
💡Plastic Chamber
A plastic chamber, as described in the script, is a container designed to hold a specific substance, in this case, liquid CO2. It is a central component of the project, serving as the vessel where the experiment takes place. The chamber is made from aluminum with an acrylic front and back, highlighting its role in the video's theme of demonstrating the properties of supercritical CO2.
💡Liquid CO2
Liquid CO2 is carbon dioxide in its liquid state, which occurs at high pressures and low temperatures. In the video, it is the substance inside the plastic chamber that undergoes a phase change when heated, illustrating the concept of supercritical fluids. The script mentions the use of a heater to induce this phase change, demonstrating the properties of liquid CO2 in a controlled environment.
💡Strip Heater
A strip heater, as mentioned in the script, is a type of flexible heating element often used for bending acrylic or heating pipes. In the context of the video, the strip heater is used to wrap around the plastic chamber, gradually increasing the temperature of the liquid CO2 inside, which is crucial for achieving the supercritical state.
💡Thermocouple
A thermocouple is a temperature measurement device, consisting of two dissimilar metals that produce a voltage when exposed to heat. In the script, a tiny hole is drilled in the chamber to insert a thermocouple for obtaining more accurate temperature readings, emphasizing the importance of precise temperature control in the experiment.
💡Pressure Gauge
A pressure gauge is an instrument used to measure the pressure of a contained substance. In the video, the pressure gauge reads about 700 PSI, indicating the pressure of the liquid CO2 inside the chamber. This measurement is vital for understanding the state of the CO2 and its transition to a supercritical fluid.
💡Supercritical Fluid
A supercritical fluid is a state of matter where distinct liquid and gas phases do not exist, and the substance has properties of both. In the script, the CO2 inside the chamber becomes a supercritical fluid as the heating process progresses, blending the liquid and gas phases into one continuous phase, which is a key point in the video's demonstration.
💡Dry Ice
Dry ice is the solid form of carbon dioxide and sublimates directly from solid to gas at room temperature. In the video, dry ice is used to cool the chamber rapidly, causing the supercritical CO2 to revert back to two distinct phases of liquid and gas, demonstrating the temperature and pressure sensitivity of supercritical fluids.
💡Acrylic
Acrylic is a type of plastic known for its transparency and strength. In the script, the chamber is constructed with acrylic on the front and back, allowing viewers to observe the changes inside the chamber as the CO2 transitions to a supercritical state, which is integral to the visual demonstration of the video.
💡O-Ring
An O-ring is a loop of elastomer with a round cross-section, designed to be compressed during assembly between two or more parts, creating a seal at the connection. In the script, the O-ring is used to seal the chamber, but it faces challenges due to the pressure build-up during the experiment, highlighting the engineering considerations in the design of the chamber.
💡Decaffeination
Decaffeination is the process of removing caffeine from coffee beans or other substances. The script mentions the potential use of supercritical CO2 for decaffeinating green coffee beans, which is an industrial application of supercritical fluids, showcasing a practical application of the concept discussed in the video.
💡Dry Cleaning
Dry cleaning refers to the cleaning process that uses solvents other than water to remove dirt and stains from fabrics. In the video, the script suggests using supercritical CO2 for dry cleaning as it can remove oily substances without the need for water or hydrocarbon solvents, illustrating another commercial application of supercritical fluids.
Highlights

Introduction of a homemade plastic chamber designed to hold liquid CO2.

Demonstration of the chamber's functionality with a strip heater for controlled heating.

Use of a flexible fiberglass covered heater typically used for bending acrylic.

The chamber is made from aluminum with acrylic front and back, designed for slow heating.

Installation of a pressure gauge to monitor the CO2 inside the chamber.

Drilling a hole for a thermacouple to get more accurate temperature readings.

Observation of CO2 boiling within the chamber as heat is applied.

Transition of CO2 from liquid to gas phase and the disappearance of the dividing line between the two.

Shaking the chamber results in a uniform phase of supercritical CO2.

Unplugging the heater to allow the cloudiness within the chamber to subside.

Using dry ice to rapidly decrease the temperature and revert CO2 back to two phases.

Description of the chamber's construction process, including machining aluminum and acrylic parts.

Challenge of filling the chamber without a valve, leading to high pressure deformation of the O-ring.

Design considerations for the thickness of acrylic based on engineering formulas and anticipated pressures.

Safety measures taken by setting up the chamber in a shop corner with a camera for remote monitoring.

Experimentation with supercritical CO2 to potentially extract caffeine from green coffee beans.

Discussion of commercial uses of supercritical CO2, such as decaffeination and dry cleaning.

Invitation for suggestions on other potential uses for supercritical CO2.

Closing remarks and sign-off for the video.

Transcripts
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