Precipitation Reactions: Crash Course Chemistry #9

CrashCourse
15 Apr 201311:31
EducationalLearning
32 Likes 10 Comments

TLDRThe video explores precipitation reactions, where chemicals dissolved in water react to form solid precipitates, using the example of how silver deposits formed in Montana's rich mineral veins. It discusses solubility of ionic compounds, how to determine cation and anion charges, and write balanced precipitation reaction equations. It then does sample calculations to determine how much sodium chloride is needed to precipitate out one troy ounce of silver from silver nitrate solution. Finally, it notes that further refining through redox reactions would be needed to extract pure silver from the silver chloride precipitate.

Takeaways
  • ๐Ÿ˜€ Precipitation reactions happen when chemicals in a solution react to form a solid precipitate.
  • ๐Ÿ‘จโ€๐Ÿ”ฌ Understanding solubility and ion charges is key to predicting precipitation reaction products.
  • ๐Ÿ”ฌ There are special ways to write precipitation reaction equations to show the state changes.
  • ๐ŸŒŠ Ocean water contains tons of dissolved gold, but it's not yet economical to extract it.
  • ๐Ÿ’ฐ Silver deposits formed from precipitation reactions between silver ions and salts over geological timescales.
  • ๐Ÿ˜ฎ Silver has been valued for purity and health since ancient times and was key to settling the American West.
  • ๐Ÿ”Ž Researchers are looking into medical uses for silver nanoparticles.
  • โš—๏ธ To make the reaction practical, you calculate how much reactant you need to produce a desired precipitant.
  • โ™ป๏ธ Getting pure silver requires additional redox reactions after the initial precipitation reaction.
  • ๐Ÿ“ Precipitation is used in water purification, mineral extraction, and bathtub ring formation!
Q & A
  • What is a precipitation reaction?

    -A precipitation reaction is a chemical reaction where two chemicals in solution react to form an insoluble solid called a precipitate.

  • Why are precipitation reactions important?

    -Precipitation reactions are important because they create geological deposits, allow us to purify water, extract metals from ores, and produce very pure chemicals.

  • What were some historical uses of silver?

    -Silver was historically used to disinfect wounds and dress burns. Ancient cultures also associated silver with purity and health.

  • How are precipitation reaction equations written?

    -Precipitation reactions can be written as molecular equations showing the states, net ionic equations showing only participating ions, or complete ionic equations showing all dissolved ions.

  • What is the difference between a precipitate and precipitate?

    -The noun 'precipitate' refers to the solid formed in a precipitation reaction. The verb 'precipitate' refers to the action of forming a solid.

  • What ions reacted to form the silver chloride precipitate in the video?

    -The silver cation and the chloride anion reacted to form solid silver chloride.

  • Why does the ocean contain so much gold?

    -The ocean contains tons of dissolved ions like gold that have been weathered from land over millions of years and accumulated in seawater.

  • Why did the script mention the troy system for weights?

    -The troy system is traditionally used to weigh precious metals and was used in the video to specify the target amount of silver to precipitate.

  • What is the next step after precipitating silver?

    -After precipitating silver as silver chloride, the next step is to refine it through a redox reaction to produce pure metallic silver.

  • Why did silver's chemical symbol Ag come from the Latin word for silver?

    -Silver's chemical symbol Ag comes from the Latin word 'argentum' which meant silver. This reflects silver's historical importance.

Outlines
00:00
๐Ÿฝ๏ธ Enjoying dinner with a werewolf friend

Paragraph 1 describes the narrator having dinner with a friend who turns into a werewolf. It talks about silver's mythical protective powers against evil creatures and its importance in American history and settlement. The paragraph then transitions to discussing chemical reactions like precipitation that deposit silver and other minerals.

05:01
๐ŸŒ€ Understanding precipitation reactions

Paragraph 2 explains basics of precipitation reactions - how solubility and ion charges dictate which solid precipitates form when aqueous solutions are mixed. It analyzes the specific reaction occurring between sodium chloride and silver nitrate to precipitate insoluble silver chloride.

10:02
๐Ÿ’ฐ Calculating the silver payout

Paragraph 3 shows calculations to determine how much sodium chloride is needed to precipitate out 31.1 grams (1 troy ounce) of silver from silver nitrate. It explains more reactions are needed to refine and isolate pure silver.

Mindmap
Keywords
๐Ÿ’กprecipitation reaction
A type of chemical reaction where two chemicals in aqueous solution react to form an insoluble solid called a precipitate. These reactions are key to understanding how silver and other geological deposits formed, which is a main theme in the video. An example is when silver nitrate and sodium chloride solutions are mixed, forming solid silver chloride.
๐Ÿ’กsolubility
A measure of how much of a substance can dissolve in a solvent like water. Solubility is key to precipitation reactions, where compounds fall out of solution as insoluble solids once solubility limits are exceeded. The video discusses water's ability to dissolve ionic compounds.
๐Ÿ’กcation
A positively charged ion, which reacts with negatively charged anions to form ionic compounds. Identifying whether ions are cations or anions helps predict the products of precipitation reactions, like realizing silver and sodium are cations.
๐Ÿ’กanion
A negatively charged ion, which reacts with positively charged cations. As discussed for "cation," knowing whether ions are anions or cations allows predicting precipitation reaction products.
๐Ÿ’กaqueous
Meaning 'in water.' An aqueous solution contains a dissolved substance like an ionic compound. Precipitation reactions start with aqueous solutions and end with insoluble solids.
๐Ÿ’กnet ionic equation
A condensed chemical equation showing only the key ions participating in a precipitation reaction. The net ionic equation simplifies full reactions by leaving out spectator ions, giving a focused view of what's reacting.
๐Ÿ’กoxidation
The loss of electrons from an atom, molecule, or ion. Oxidation is one half of a redox reaction, which will be covered later. Redox reactions allow retrieving pure silver from the silver chloride precipitate.
๐Ÿ’กreduction
The gaining of electrons by an atom, molecule, or ion. Reduction is paired with oxidation in redox reactions, which will extract pure silver from the precipitated silver chloride as a next step.
๐Ÿ’กstoichiometry
The calculation of quantitative relationships between reactants and products in a chemical reaction. The video performs stoichiometric calculations to determine how much sodium chloride is needed to precipitate out a desired quantity of silver.
๐Ÿ’กmolar mass
The mass in grams of one mole of a substance. Molar masses are used in the stoichiometric calculations relating sodium chloride reactant to silver precipitate product.
Highlights

Precipitation is stuff falling out of other stuff: water falling out of the sky, solids falling out of solution.

Some ionic compounds can overcome even the dissolving power of water, and when they form through reactions in solution, they fall out as a solid precipitate.

The key to understanding what just happened here is that both of the compounds are ionic.

We're left with silver chloride. Just process of elimination.

Unlike salt though it's not very soluble in water.

There are special ways to write and balance them as equations.

If we wanted to get the silver out of solution, how much salt would we need?

Silver nitrate and a compound called silver sulfadiazine were used to disinfect wounds in World War I, before antibiotics were discovered.

Some people even take colloidal silver, basically silver particles in a liquid suspension, as a kind of general health booster.

In our case, there's another type of reaction necessary called a redox reaction. Redox is short for reduction-oxidation and that is what we'll be talking about next time.

We discussed what defines precipitation reactions, and how you can determine what precipitants they form.

We also learned how to write precipitate reaction equations.

We calculated a molar mass equation to figure out how much of a reactant we need to produce a desired amount of precipitant.

Our chemistry consultant is Dr. Heiko Langner.

This episode was filmed and directed and edited by Nicholas Jenkins with sound design by Michael Aranda.

Transcripts
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